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Geological sequestration of carbon dioxide = thermodynamics, kinetics, and reaction path modeling /

紀錄類型:	書目-電子資源 : 單行本
正題名/作者:	Geological sequestration of carbon dioxide/ Luigi Marini.
其他題名:	thermodynamics, kinetics, and reaction path modeling /
作者:	Marini, Luigi,
出版者:	Amsterdam ;Elsevier, : 2007.,
面頁冊數:	1 online resource (xv, 453 p.) :ill. :
標題:	Carbon dioxide. -
電子資源:	http://www.sciencedirect.com/science/book/9780444529503
ISBN:	9780444529503

Geological sequestration of carbon dioxide = thermodynamics, kinetics, and reaction path modeling /
Marini, Luigi,1953-

Geological sequestration of carbon dioxidethermodynamics, kinetics, and reaction path modeling /[electronic resource] :Luigi Marini. - Amsterdam ;Elsevier,2007. - 1 online resource (xv, 453 p.) :ill. - Developments in geochemistry ;11. - Developments in geochemistry ;11..

Includes bibliographical references and index.

Preface. 1. Why we should care: the impact of anthropogenic carbon dioxide on the carbon cycle. 2. The thermodynamic background. 3. Carbon dioxide and CO2-H2O mixtures. -- 4. The aqueous electrolytic solution. 5. The product solid phases. 6. The kinetics of mineral carbonation. 7. Reaction path modeling of geological CO2 sequestration.

The contents of this monograph are two-scope. First, it intends to provide a synthetic but complete account of the thermodynamic and kinetic foundations on which the reaction path modeling of geological CO2 sequestration is based. In particular, a great effort is devoted to review the thermodynamic properties of CO2 and of the CO2-H2O system and the interactions in the aqueous solution, the thermodynamic stability of solid product phases (by means of several stability plots and activity plots), the volumes of carbonation reactions, and especially the kinetics of dissolution/precipitation reactions of silicates, oxides, hydroxides, and carbonates. Second, it intends to show the reader how reaction path modeling of geological CO2 sequestration is carried out. To this purpose the well-known high-quality EQ3/6 software package is used. Setting up of computer simulations and obtained results are described in detail and used EQ3/6 input files are given to guide the reader step-by-step from the beginning to the end of these exercises. Finally, some examples of reaction-path- and reaction-transport-modeling taken from the available literature are presented. The results of these simulations are of fundamental importance to evaluate the amounts of potentially sequestered CO2, and their evolution with time, as well as the time changes of all the other relevant geochemical parameters (e.g., amounts of solid reactants and products, composition of the aqueous phase, pH, redox potential, effects on aquifer porosity). In other words, in this way we are able to predict what occurs when CO2 is injected into a deep aquifer. * Provides applications for investigating and predicting geological carbon dioxide sequestration * Reviews the geochemical literature in the field * Discusses the importance of geochemists in the multidisciplinary study of geological carbon dioxide sequestration.

ISBN: 9780444529503

Source: 135612:135747Elsevier Science & Technologyhttp://www.sciencedirect.comSubjects--Topical Terms:

323921
Carbon dioxide.
Index Terms--Genre/Form:

96803
Electronic books.

LC Class. No.: QE516.5 / .M37 2007eb

Dewey Class. No.: 553.2

Geological sequestration of carbon dioxide = thermodynamics, kinetics, and reaction path modeling /
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245 1 0 $a Geological sequestration of carbon dioxide $h [electronic resource] : $b thermodynamics, kinetics, and reaction path modeling / $c Luigi Marini.
260 $a Amsterdam ; $a Oxford : $c 2007. $b Elsevier,
300 $a 1 online resource (xv, 453 p.) : $b ill.
490 1 $a Developments in geochemistry ; $v 11
504 $a Includes bibliographical references and index.
505 0 $a Preface. 1. Why we should care: the impact of anthropogenic carbon dioxide on the carbon cycle. 2. The thermodynamic background. 3. Carbon dioxide and CO2-H2O mixtures. -- 4. The aqueous electrolytic solution. 5. The product solid phases. 6. The kinetics of mineral carbonation. 7. Reaction path modeling of geological CO2 sequestration.
520 $a The contents of this monograph are two-scope. First, it intends to provide a synthetic but complete account of the thermodynamic and kinetic foundations on which the reaction path modeling of geological CO2 sequestration is based. In particular, a great effort is devoted to review the thermodynamic properties of CO2 and of the CO2-H2O system and the interactions in the aqueous solution, the thermodynamic stability of solid product phases (by means of several stability plots and activity plots), the volumes of carbonation reactions, and especially the kinetics of dissolution/precipitation reactions of silicates, oxides, hydroxides, and carbonates. Second, it intends to show the reader how reaction path modeling of geological CO2 sequestration is carried out. To this purpose the well-known high-quality EQ3/6 software package is used. Setting up of computer simulations and obtained results are described in detail and used EQ3/6 input files are given to guide the reader step-by-step from the beginning to the end of these exercises. Finally, some examples of reaction-path- and reaction-transport-modeling taken from the available literature are presented. The results of these simulations are of fundamental importance to evaluate the amounts of potentially sequestered CO2, and their evolution with time, as well as the time changes of all the other relevant geochemical parameters (e.g., amounts of solid reactants and products, composition of the aqueous phase, pH, redox potential, effects on aquifer porosity). In other words, in this way we are able to predict what occurs when CO2 is injected into a deep aquifer. * Provides applications for investigating and predicting geological carbon dioxide sequestration * Reviews the geochemical literature in the field * Discusses the importance of geochemists in the multidisciplinary study of geological carbon dioxide sequestration.
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830 0 $a Developments in geochemistry ; $v 11. $3 323919
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